TPH brochure

TPH brochure

Standards for TPH Analysis

AccuStandard®, Inc.

Calibrate on AccuStandard forTPH Analysis... •Offers the Largest Library of Pattern Identification Fuel Standards providing easy confirmationof subtle fuel differences.

•First company to offer ready-to-inject calibration curves, which eliminates standard preparation time, insuring precision & accuracy. •Convenient Setsfor Specific Fuel applications.

•Weathered Fuel Sets help solve the problemof identification and estimation of total gross hydrocarbon concentrations in a sample.

•Speciation standardsare available for volatile Aromatic, Aliphatic and extractable PAH analysis involving Gasoline, Diesel and

Residual Range Organics (GRO, DRO & RRO). •Bulk Packagingto meet specific laboratory sample demands.

•New PTsample formulationsfor laboratory TPH certification as well as for meeting new regulatory requirements.

•Specialistsin State-Specific Standards for UST/LUFT/LUSTMethods covering:

Alaska California Florida Mississippi Tennessee Massachusetts Pennsylvania Texas Washington Wisconsin

The only manufacturerwith an Aliphatic Hydrocarbon Window Defining Standard containing even and odd Alkanes that has multistate applications (Cat. # DRH-008S). One Standard Does It All!

Calibrate on US! As do many Government, State, Commercial labs, and Instrument Manufacturers who trust AccuStandard’s TPH Calibration Standards.

US NavyCaliforniaAgilentSevern Trent US EPA Maryland Varian Chevron US Coast GuardFloridaTest AmericaCeimic

AccuStandard®

Phone: 203-786-5290 FAX: 203-786-5287 E-Mail: usa@accustandard.com Toll Free: 800-442-5290 Toll Free: 877-786-5287 Web Site: w.accustandard.com

The Comprehensive Source...

AccuStandard offers the widest selection - over 27,0 standards.

Save time by consolidating your procurement of standards. Save more time by ordering on the easiest website (w.accustandard.com)

Call today for your free catalogs in each of the three areas: Organic, Inorganic, and Petroleum. Fax or e-mail your requirements for an immediate quote.

ISO 9001

Cover TPH Photo (Tank removal) Courtesy of Connecticut DEP

Based on using the DRH-008Sstandard containing the straight chain Alkanes from C8 to C40, a window can be established where the Petrochemical product would be present in the chromatogram. This defined Alkane window is useful to quickly identify weathered or multiple Petrochemical products by the hydrocarbon window they encompass.

Single Source Contamination

Defining a specific Petrochemical pattern to a known Alkane hydrocarbon range allows the chemist to calculate a Gross Hydrocarbon concentration using the Petrochemical calibration standard that is the closest match.

The hydrocarbon range defines the starting and end points used to establish an area response or actual response factor for each Petrochemical calibration standard. Quantification of the sample by other laboratories using the same standardized Alkane defined window should yield similar results.

Multiple Source orWeathered Contamination

This technique is very useful for weathered or mixed fuel patterns (gasoline/diesel) where a gross hydrocarbon concentration is being established for each of the fuels present in the soil or water sample. Better inter-laboratory reproducibility can be achieved by defining the window segment for each fuel in a mixed fuel sample (gasoline portion/diesel portion) and quantifying the defined segment with that same representative portion from the actual Petrochemical calibration standard.Calibrate on UsforTPH Identification

Analytical chemists need to identify Petrochemical spills. They also have to quantify the gross hydrocarbon concentration. This decision-making process becomes even more challenging if the Petrochemical product has weathered in the environment or if multiple petrochemical products have spilled or leaked at the sampling site.

AccuStandard has prepared a select group of representative Petrochemical products (Cat. # TPH-SET) typically found when leaking or spill assessment Phase 1, 2, or 3 site investigation is conducted.

The TPH Technical Reference Guide (Cat. # BOOK-TPH) allows the chemist to identify the Petrochemical product against reference chromatography for various related Petroleum products found during UST/LUFT/LUSTsite investigation. The Petrochemical reference standards (Cat. # TPH-SET) presented in the TPH book were analyzed by an optimized set of operating conditions to allow good pattern recognition in under a half hour and to establish a defined C8 to C40 Alkane hydrocarbon window.

PATTERN RECOGNITION STANDARDS AccuStandard, Inc.

Use of the reference guide in conjunction with the TPH pattern Identification Standards (Cat. # TPH-SET) optimizes identification of laboratory samples. In addition, the chromatography in the book shows each fuel pattern and an overlay to our Multi State Window Defining Standard (Cat. # DRH-008S).

The DRH-008S"Window Defining Standard" is used to establish the beginning and ending points in the Petrochemical chromatogram.

To OrderTPH Book Use Cat. #BOOK-TPH$ 35

Hydrocarbon Window Defining Standard

Octane Nonane Decane Undecane Dodecane Tridecane Tetradecane Pentadecane Hexadecane Heptadecane Octadecane Pristane

Nonadecane Phytane Eicosane Heneicosane Docosane Tricosane Tetracosane Pentacosane Hexacosane Heptacosane Octacosane Nonacosane

Triacontane n-Hentriacontane Dotriacontane Tritriacontane Tetratriacontane Pentatriacontane Hexatriacontane Heptatriacontane Octatriacontane Nonatriacontane Tetracontane

DRH-008S$ 65 / 1 x 1 mL DRH-008S-PAKSAVE 20%$ 260 / 5 x 1 mL 500 µg/mLeach in CS2:CH2Cl2 (3:1)35 comps.

Phone: 203-786-5290 FAX: 203-786-5287 E-Mail: usa@accustandard.com Toll Free: 800-442-5290 Toll Free: 877-786-5287 Web Site: w.accustandard.com

WP-PT Oil, Grease & TPH

IPE-OILG-001-AS *$ 30 / 5 mL IPE-OILG-001-AT *$ 30 / 5 mL IPE-OILG-001-AV *$ 30 / 5 mL

Sample conc. after prep Contains 2 analytes listed below

Analyte ListSample range Total Oil & Grease †5-100 mg/L TPH5-100 mg/L

Technical Note

To be used by gravimetric oil and grease methods. In addition, this PTsample can now be used for TPH analysis by gravimetric methods including the EPA method 1664. The sample contains real world material typically present in the environment.

Method 1664 Oil, Grease & TPH

M-1664-5ML$ 15 / 1 x 5 mL M-1664-5ML-PAKSAVE 20%$ 60 / 5 x 5 mL 4.0 mg/mLeach in Acetone2 comps.

Hexadecane Stearic acid

Method 413.2 & 418.1 TPH Analyis by IR

Oil, Grease & Petroleum Hydrocarbon Concentrates Mix M-418-CON$ 35 / 1 x 1 mL % by volume3 comps.

Chlorobenzene (25.0) Isooctane (37.5) Hexadecane (37.5)

New PTSamples Gasoline & Diesel

The new Gasoline PTsample allows laboratories to test for gasoline TPH. This sample can also be used to test for the BTEX concentrations so the lab can use this product for method 602, 8020, 8021 and 8015 modified. Reduce analytical bias by using the recommended calibration standard listed with the PTsample when conducting PTstudies. AccuStandard is the one ISO 9001 standard manufacturer capable of supplying not only the PTsample(s), but also a wide variety of calibration standards to meet your specific TPH requirement.

Technical Note

AccuStandard's Precison and Recovery (PAR) Spiking Solution was developed for the new Method 1664. This performance based method was developed to replace gravimetric procedures which had Freon-113 as the extraction solvent. Each standard is packaged in a flame sealed ampule conveniently sized for quality control of the analytical batch.

Oil, Grease and Petroleum Hydrocarbon Working Standard M-418$ 30 / 1 x 1 mL M-418-PAKSAVE 20%$ 120 / 5 x 1 mL Total 4.15 mg/mLin Freon 113, (Parts by volume)3 comps.

Chlorobenzene (10.0) n-Hexadecane (15.0) Isooctane (15.0)

* Designed for CA/ NELAC

PT Samples

Gasoline with BTEX OPE-CGAS-001-AS$ 70 / 2 mL OPE-CGAS-001-AT$ 70 / 2 mL OPE-CGAS-001-AV$ 70 / 2 mL Sample conc. after prep 0.1-5 mg/mL Contains 5 analytes listed below

#2 Diesel OPE-DIESEL-001-AS$ 70 / 2 mL OPE-DIESEL-001-AT$ 70 / 2 mL OPE-DIESEL-001-AV$ 70 / 2 mL Sample conc. after prep 0.1-5 mg/mL Contains analyte listed below

Diesel

Proficiency Test Sample

Formal Studies Quick Turnaround QA/QC

Proficiency Test Sample

Formal Studies Quick Turnaround QA/QC

Gasoline Benzene Toluene

Ethyl benzene Total Xylene

Accredited by the National Voluntary Laboratory Accredition Program for the specific scope of accrediation under Lab Code 200389-0

Suggested Calibration Standards

GA-001-40X$ 20 / 1 mL Regular Unleaded Gasoline @ 20 mg/mLin MeOH

M-602-GAS-10X$ 30 / 1 mL Purgeable Aromatics (BTEX) with Oxygenate - Gasoline ID

Suggested Calibration Standard

FU-009-40X$ 20 / 1 mL #2 Diesel @ 20 mg/mLin MeOH

Proficiency Test Sample

Formal Studies Quick Turnaround QA/QC

M-1664-20ML$ 25 / 1 x 20 mL M-1664-20ML-PAKSAVE 20%$ 100 / 5 x 20 mL 4.0 mg/mLeach in Acetone2 comps.

Hexadecane Stearic acid

TPH Pattern Recognition Standards

TPH-SET$ 535 / 3 x 1 mL The set contains the following fuel products @ 20 mg/mLin Methylene chloride

Aviation Fuels & Oils

Aviation(gas) Grade 100 L JP-4 Fuel JP-5 Fuel JP-7 Fuel JP-8 Fuel JP-10 Fuel (Cruise Missile) JP-TS Jet Fuel (type 1) Turbine (Jet A) Fuel Hydraulic oil

Household Industrial Solvents

Lacquer thinner Mineral spirits Naphtha Turpentine Stoddard

Oxygenate PTSamples

With MtBE contamination problems in drinking water, numerous states are now requiring certification for Oxygenate monitoring. Join AccuStandard’s next study for Oxygenate analysis. Our timely PTschedule easily allows your lab to be proactive in new regulatory requirements. The analytes in the standard and the PT sample have been drawn from the California list of known prevalent oxygenates in gasoline. These new Oxygenate standards allow your Lab to:

• Expand testing capabilities • Generate new testing revenue

• Eliminate standard preparation

• Easily combine with otherAccuStandard Volatile standards.

Motor Fuels & Lubricating Oils

Regular unleaded gasoline Regular leaded gasoline Premium gasoline RFAGasoline (oxygenate free) #2 Diesel (conventional)

#1 Diesel (low sulfur)

#2 Diesel (extra-low sulfur) Artic Diesel SAE 30 W motor oil SAE 40 W motor oil SAE 50 W motor oil

Heating Fuel Oils

#1 Fuel Oil #2 Fuel Oil

#3 Fuel Oil

#4 Fuel Oil

#5 Fuel Oil

#6 Fuel Oil Kerosene

Purgeable Aromatics with Oxygenate - Gasoline ID

Benzene Chlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Ethylbenzene

Toluene o-Xylene p-Xylene m-Xylene MtBE

Certified BTEX

Certified BTEX in Unleaded Gasoline (Single Source) GA-001-20X-BTEX$ 5 / 1 x 1 mL 10.0 mg/mLin MeOH

Gasoline - Regular, unleaded

Certified BTEX in Gasoline Composite Mix (Multi Source) AK-101.0-GCS-BTEX$ 5 / 1 x 1 mL 5 mg/mLtotal in MeOH3 comps.

Gasoline - Premium (1.6 mg/mL) Gasoline - Regular, leaded (1.67 mg/mL) Gasoline - Regular, unleaded (1.67 mg/mL)

Technical Note

Simultaneous BTEX / Gasoline QA/QC AccuStandard's QA/QC department has certified the benzene, toluene, ethyl benzene and xylene concentrations in our unleaded gasoline standard (GA-001-20X-BTEX& in AK-101.0-GCS-BTEX). Use of either standard allows the analytical chemist with a single injection to verify that QA/QC requirements are being met for the BTEX analytes as well as for the gasoline.

Since formulating the standards for the Alaskan method and due to numerous laboratory requests, we have added a new multi-source certified BTEX in gasoline composite mix (AK-101.0-GCS-BTEX). The BTEX values for this multi-source calibration standard have been determined through in-house analysis against a BTEX multi-level calibration curve, and are listed on the Certificate.

MtBE(2000 µg/mL) ETBE(2000 µg/mL) Isopropyl ether(2000 µg/mL)

Oxygenate Gasoline Additives

OGAD-001$ 30 / 1 x 1 mL OGAD-001-PAKSAVE 20%$ 120 / 5 x 1 mL At stated conc. in MeOH5 comps.

TAME(2000 µg/mL) t-Butanol (10000 µg/mL)

Gasoline/Diesel Calibration Solutions

Gasoline/Diesel Composite Standards

AccuStandard continues to offer ready-to-use working level standards to meet mandatory TPH methods. These new Multi-Fuel calibration standards and curve make it easier for the chemist to identify mixed fuel sources and to estimate the actual concentration of both the gasoline and diesel portions. Contact us for new Texas method 1005 & 1006 standards under development.

WS-PT Oxygenates OPE-OXY-001-AS$ 45 / 2 mL OPE-OXY-001-AT$ 45 / 2 mL OPE-OXY-001-AV$ 45 / 2 mL Sample conc. after prep 5.0-50 µg/L Contains 4 analytes listed below

ETBEDiisopropylether MTBE TAME

DRH-TX-002-D-40X$ 25 / 1 x 1 mL DRH-TX-002-D-40X-PAKSAVE 20%$ 100 / 5 x 1 mL

20,0 µg/mLeach in CH2Cl22 comps.

Gasoline - Regular, unleaded #2 Diesel Fuel

DRH-TX-002-10X$ 25 / 1 x 1 mL DRH-TX-002-10X-PAKSAVE 20%$ 100 / 5 x 1 mL 5000 µg/mLeach in MeOH2 comps.

Gasoline - Regular, unleaded #2 Diesel Fuel

DRH-TX-002-D-SET$ 75 / 8 x 1 mL Each mix contains: Regular, Unleaded Gasoline & #2 Diesel Fuel

Cat. #Conc.Solvent

DRH-TX-002-D-0.01X 5 µg/mL CH2Cl2 DRH-TX-002-D-0.04X 20 µg/mL CH2Cl2 DRH-TX-002-D-0.1X 50 µg/mL CH2Cl2 DRH-TX-002-D-0.2X 100 µg/mL CH2Cl2 DRH-TX-002-D-0.4X 200 µg/mL CH2Cl2 DRH-TX-002-D-1X 500 µg/mL CH2Cl2 DRH-TX-002-D-2X 1000 µg/mL CH2Cl2 DRH-TX-002-D-10X 5000 µg/mL CH2Cl2

Formal Studies

Quick Turn Around QA/QC

M-602-GAS-10X$ 30 / 1 x 1 mL 2.0 mg/mLeach in MeOH11 comps.

AccuStandard, Inc. 125 Market Street New Haven, CT06513 USA

Address Service Requested

AccuStandard®

TPH Analysis

PRSRT STD U.S. POSTAGE PAID NEW HAVEN, CT PERMITNO. 360

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